Activation Parameter and Solvent Effect on Solvolysis of Ethyl Benzoate in Aquo-Organic Solvent System.

Activation Parameter and Solvent Effect on Solvolysis of Ethyl Benzoate in Aquo-Organic Solvent System.

Blog Article

The rate of hydrolysis of hydrolysis of ethyl benzoate were measured volumetric over the temperature range of 200c to 400c.in water-methanol mixture at different composition.The different solvation in initial and transition state is due to L-Arginine decrease in rate with varying the composition of mixture.The influence of solvent on reaction rate was examined in term of activation parameter.The increase in values of DG* and simultaneous depletion in values of DH* and DS* with solvent composition reveals that the reaction is Enthalpy Nail Dry Oil domination and Entropy controlled.

The value of iso-kinetic temperature is less than 300 shows the weak interaction between solvent and solute.